| Sep 8 | @ Borussia Dortmund | Signal Iduna Park, AueCBSSN, Paramount+ |
| Oct 13 | vs Napoli | Estadio de la Cerámica, VillarrealParamount+ |
| Oct 20 | @ Liverpool | Anfield, LiverpoolParamount+ |
| Nov 3 | vs Paris Saint-Germain | Estadio de la Cerámica, VillarrealParamount+ |
| When | Matchup | Venue and broadcast |
|---|---|---|
| Nov 25 | @ Slavia Prague | Fortuna Arena, PragueParamount+ |
| Dec 8 | vs Sabah FK | Estadio de la Cerámica, VillarrealParamount+ |
| Jan 20 | @ Fenerbahce | Şükrü Saracoğlu Stadium, IstanbulParamount+ |
| Jan 27 | vs Manchester United | Estadio de la Cerámica, VillarrealParamount+ |